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Something instead of Resin Pu ? Allergic problem.

Jul 6, 2010

    1. Hi every one.

      I am really worried because it is sure that I am allergic to resin PU. I have problem each time I work with it on her liquid form, less when it is hard. But I can't continue making doll in Resin PU if each time I use it I am sick.
      So wanted to ask here if you know something that can be use instead of Resin PU, and can be work with silicon mold.
      Does someone here test bioresin ?
      I have a look on the web but don't see what I can use that will be less toxic than Resin PU but with the same property.
      I can't stop making doll as it is my work, but using Resin is really a problem. :(
      Thanks by advance for your answer.
       
    2. I haven't been able to obtain any samples of Bioresin, and I am not sure if it would affect your allergy problem or not. The only distributor I could find was in the UK, and the German contact (I believe it is manufactured in Germany) did not respond to my enquiries.
       
    3. :s well it is true that it isn't sure that it will fix my allergy problem :( I'm really sad, there is a french distributor www.bioresin.fr I'll call them this morning to discuss with them of their product. Hope that they could purpose my something interesting. I will let you know.
       
    4. It seems less "user-friendly" than resin, but... porcelain? . Marina Bychkova seems to be very successful with her porcelain dolls: Enchanted Doll.

      Another possibility would be to have a company do your casting. There was some discussion of that here.

      Your work is lovely, I hope you find a way to continue doing it!
       
    5. Hi morgan thanks for your answer.
      Yes there is porcelain but I would have to change totally the way I work.. It suppose plaster mold and things like that.
      I call Bioresin yesterday, the man I had on the phone told me that their resin is more liquid that pu resin I used. It seems to be a really good product but... it is TOO expensive.
      Price is 42euros per KG and they sale kit of 10 kg..; So unfortunately it is 4 times more expensive that regular resin and way too expensive to make doll.
      I made search and finally try yesterday something I have at home and never get the time to try. I don't know exactly what is the name of this. It is a sort of Ceramic powder that can be used in silicon mold, you can color it. So I made a try on an headback and it is stronger than resin, hard like a stone. Really impressive ! It looks a little bit like porcelain. And it is user friendly so great for me.
      I think I will try on a complete doll and see.
      Morgan I allready in contact with a manufacturer for my doll, and have one that will be for sale very soon, but I want to continue making art doll, fully made by hand and a manufacturer can't do that for me. There are two different things.
       
    6. Lillycat I would love to know more about the ceramic powder product, so any information you could give to provide enlightenment would be great. I agree that the Bioresin is expensive. I wish we could find out more about the "environmental resin" that some companies such as BlueBloodDolls are using....
       
    7. Yes it is really sad that bioresin is so expensive :(
      Well The ceramic powder I found, look like plaster, but really thiner. You mix it with water, and you can add liquid color or powder color in it so the color will be in the whole piece.
      I don't find what it is exactly. The french name is artestone. I copy you the english text that I have.

      Artestone is a hight quality ceramic casting powder, which is manufactured on the basis of phosphates.
      Form parts made of artestone are distinguished by their extremely hard and solid and yet abrasion resistant surface.
      Hydrophate is also mixed into the artestone which means that the cast parts do not absorb any liquids when they are dry.
      You can cast it in silicon mold.
      adding color in the casting mixture with universal color concentrate.
      You can made it looks like china by casting past primer and glaze them with a transparent cold glaze.


      I think it looks really interesting, because I don't want to work with porcelain. And need something really strong.
      But this means really doll art, as I isn't possible to remove the paint and it means finding another way to work on doll.
      But it could be great.
       
    8. technic information :
      mixing ration : 4:1 water
      casting time hardening start 8/10 minutes
      expansion controlled 0.2%
      surface hardness dry : 315N/mm2
      compressive strength dry : 75N/mm2
      flectionnal strength dry : over14N/mm2

      temperature resistance dry : up to 130 °c


      there is also another product call kersolith that is use to make hollow form with the same technic as porcelain.

      safety :

      artestone is free of any dangerous components. Children over the age of 5 years can work with artestone under the supervision of adults. Do not inhale or swallow the powder.
       
    9. #9 twigling, Jul 8, 2010
      Last edited by a moderator: Jul 8, 2010
    10. Twenty-some years ago I made some very small dolls with a product called CompoBell CS-1000 doll composition slip which was used in a similar way to porcelain slip, in that it was cast into plaster piece molds, allowed to thicken to the desired thickness, then the excess was poured out of the plaster mold. The casting went through similar stages of curing as porcelain, such as leather-hard stage, and bone-dry stage. It could be sanded and drilled. The best part was, it was baked in the kitchen oven to achieve final hardness, similar to today's polyform clays.

      There used-to-be three main doll composition slips: Duncan, Seeley, and CompoBell. I am currently looking into buying a case (4 gallons) of it.
      Seeley was sold, and no longer seems to make doll composition slip.
      CompoBell used to be in Florida, but was sold, and is now located in Texas.
      I'm still looking for a Duncan distributor close enough that the S&H charges won't be more than the slip.

      If I'm not mistaken, doll composition slip is a vinyl slip. However, the vinyl is not the soft kind of vinyl that most people think of when they think of dolls, but it is hard after being baked.
      KW
       
    11. These are very interesting. Good thing we are scattered across the globe. So many materials...
      Tell us how things go once you finish, please. :)
       
    12. twigling> what do you think about it ? Does it sound great to you ? As I Know you are a pro about casting material and other things like that I am interested in your opinion about technical information I put here.

      Kwmelvin> oh yes I know this material. It is also call cold porcelain, they sell that on miniworld website. But it is necessary to use plaster mold for this, and it look so difficult to make :s
      it was seeley so they don't make sleap anymore.

      The only thing I see now that can be annoying with artestone is his weight it is really really heavy compare to resin, so it could be a problem with big doll, and could modify the balance of the doll.

      I will make a junk cast of Sandre to see how it look on an whole doll.
       
    13. Lillycat, I would have to take a measure of the material by testing it, but that is not possible for me right now. I would compare to resin; if you try to flex a thin part like a finger, it should not snap off, but maybe bend a little and then return to natural position when you let go. Anything that you could break with your own hands would be no good for my dolls, as they do tend to have some thin areas. The fact that this material can be poured in silicone molds is good. I don't mind a heavier doll for artist casts, but one could do a slush cast (with the kersolith), or even do a few thin layers of "heavy" material and then fill with something that has been mixed with microballoons on the inside, if there was a desire to reduce weight.
       
    14. yes it is necessary to make a test.
      Well I try and it is a little complicated to color artestone.
      I have also thought of "plâtre synthétique" Synthétic plaster that looks like porcelain, but stronger I can be poor into silicon mold. Need to try this too.
      Twigling I have try artestone on a hand of Sandre, the hand is beautiful, I let it fall on the ground and it didn't broke but if I try to broke the finger they broke. In another way if you try to do that with a porcelain doll the finger will broke too so I don't know..
       
    15. I went to an open studio night at Cockpit Arts and saw a woman who made jewelry from Bioresins. I really loved the look of it and might buy some to test. Although, I live in a small flat and was wondering is it really that non-toxic that I could leave it on the windowsill to set or do I still take precautions (same for silicone)? also, would it be unwise to use it as my first-ever casting material?
       
    16. Jphobia, you'd have to read the MSDS. Did you talk to the woman about how she uses it? From what I've read Bioresin is quite viscous so you are best off to pressurise it if you want to avoid bubbles etc. You'd still want to wear gloves and work in a well ventilated room. If you can find out what sort of base it is made from you might be able to figure out the appropriate sort of thinners to add to lower the viscosity. I'm pretty sure it would be safe to cure on the windowsill as long as no kids of pets can get to it, but I'm just not sure the results would be any good.
       
    17. Ahh, that's a shame. I'll stick to the regular kind for now until I can afford a compressor. Thanks a lot though. ^^
       
    18. Hey, while searching through these threads and reading about bioresin, I came across this product: http://www.wonderlandmodels.com/products/hobby-time-bio-resin-750ml-clear-casting-resin/ which is called 'Bio Resin', but I'm wondering if it is bio resin as in made from natural ingredients (like the other products mentioned in this thread) or something else. The description is really vague: 'a modified clear casting resin'. I've looked at the resin offered by Canonbury Arts: https://secure.canonburyarts.co.uk/supplies/bioresin/ but the hardener still contains isocyanate, so it's still too risky for me :(

      I think I'm going to try Artestone because it can be cast in silicone moulds. It sounds promising.
       
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